2 edition of Organic fluorine chemistry found in the catalog.
Organic fluorine chemistry
1971 by Plenum .
Written in English
|Statement||by M. Hudlicky.|
In the so-called Lewis theory of acids and bases, a "Lewis acid" is an electron-pair acceptor and a "Lewis base" is an electron-pair donor. These molecules are of interest across the wide spectrum of industrial and academic organic chemistry, from pharmaceuticals, through fine and specialty chemicals to polymers. Industrial Chemistry Back cover copy The introduction of carbon - fluorine bonds into organic compounds can profoundly influence their chemical and physical properties when compared to their non-fluorine containing analogues, leading to a range of man-made materials with highly desirable properties. I have been reworking the fluorocarbon page.
The author is to be commended for succinctly covering a diverse and interdisciplinary field in a systematic approach. Like this section: Hydrofluorocarbons Hydrofluorocarbons, compounds that contain only one or a few fluorine atoms, are the more common type of organofluorine compounds. ICFCA Dot structures are useful in illustrating simple covalent molecules, but the limitations of dot structures become obvious when diagramming even relatively simple organic molecules.
Equally pressing, and an area where you may have useful knowledge, is the newly fledged carbon-fluorine bond. Each reaction can be analyzed in the lab without the help of the second section, however if a solution is not easily reached, the second section provides discussion of the problems, outlining the products of the reactions and their mechanisms. Given the flexibility of informal English grammar, some people may use organofluorine as a noun to mean organofluorine compound, as evidenced by the plural "organofluorines", but besides looking too informal and being less common 50 Google books hits for "organofluorines" vs for "organofluorine compounds"the use of organofluorine as a noun would not be more general in any way. Because of the compound's effect on climate, the G major economies agreed in to support initiatives to phase out use of HCFCs. Merging, IMHO, is unwise at best. Because pharmaceuticals and fluoroacetic acid are not fluorocarbons, and I think a short page on C-F bond containing molecules is in order.
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All angles of organofluorine chemistry would be welcomed in an organoflorine compounds page. No time to add it myself now. Or someone else interested.
Inhaler propellant[ edit ] Fluorocarbons are also used as a propellant for metered-dose inhalers used to administer some asthma medications.
I am looking forward to learning more about organofluorine chemistry. Materials science[ edit ] Organofluorine compounds enjoy many niche applications in materials science. Inhe coined the term "photon" for the smallest unit of radiant energy.
In this title, other topics include: the characteristics of fluorocarbon groups in terms of ions, acids, and bases; substitution effects of fluorocarbon groups on nucleophilic displacement; elimination reactions; flouroalkane, functional, and polyfluoroaromatic compounds; fluorine in biochemistry; and, organometallic reagents.
Some organofluorine compounds pose significant risks and dangers to health and the environment. The only reason the organofluorine article exists is because it is a POV forksomething which goes against policy.
The U. With applications that extend from pharmaceuticals to fine and specialty chemicals to polymers, "Fluorine in Organic Chemistry" is an excellent reference for all organic chemists.
In this new book the author, internationally known for his contribution to organic fluorine chemistry, covers both the preparative methodologies and chemical properties of partially and highly fluorinated organic systems. A number of selected high-impact full text papers will also be considered for the special journal issues.
He had one daughter and two sons; both of his sons became chemistry professors themselves. The polymeric analogue of triflic acid, nafion is a solid acid that is used as the membrane in most low temperature fuel cells.
However, few fluorinated materials have been put to commercial use. Because pharmaceuticals and fluoroacetic acid are not fluorocarbons, and I think a short page on C-F bond containing molecules is in order.
In the spirit of merging, we should pick the most inclusive term. HFCs are potent greenhouse gases and are facing calls for stricter international regulation and phase out schedules as a fast-acting greenhouse emission abatement measure, as are perfluorocarbons PFCsand sulphur hexafluoride SF6.
The dot structures have no ability to represent the actual physical orientation of molecules, and they become overly cumbersome when more than three or four atoms are represented. The use of the C-F bond in pharmaceuticals is predicated on this altered reactivity.
If in the end some sections in this article become so big that they could warrant an own article then they can easily be split of, but for now I am afraid the two articles are going to tell a lot of duplicate information.Fluorine Chemistry for Organic Chemists Problems and Solutions Milos Hudlic'ky.
This book contains examples of the unpredictable properties of fluorine and its compounds. The reactions are given as problems in the first part of the book. In the second, solutions are offered and mechanisms of the reactions are discussed.
This book is a synthesis of two of Hudlicky's earlier books outlining the many unpredictable properties of fluorine and its compounds that are not analogous to the properties of any other halogens and their compounds.
It is divided into two separate sections, the first presenting peculiar Price: $ Among the reactions outlined are the introduction of fluorine into organic molecules, reduction and oxidation of fluorine compounds, reactions of fluorocompounds with halogens and their derivatives, nitration, acid catalyzed reactions, organometallic syntheses, and atlasbowling.com by: 2.
The present book is essentially based on the lectures on the chemistry of organic compounds of fluorine that I gave in at Virginia Polytechnic Institute in Blacksburg, Virginia, as a graduate course. References to material published to the end of are atlasbowling.com by: V.
P. Kukhar, in Fluorine - Containing Amino Acids (Eds.: V.
P. Kukhar, V. A. Soloshonok), John Wiley & Sons Ltd, Chichester, England,pp. Key Words: F. Organofluorine Chemistry will help chemists to develop a systematic knowledge of the chemistry of fluorine with a view towards its application in the design of new reactions and syntheses, and the creation of novel fluorinated molecules and materials.